[Ni(cod)(2)][Al(OR(F))(4)], a Source for Naked Ni(I) Chemistry

The straightforward synthesis of the cationic, purely organometallic Ni(I)-salt [Ni(cod)(2)](+)[Al(OR(F))(4)](–) was realized through a reaction between Ni(cod)(2) and Ag[Al(OR(F))(4)]. Crystal structure, EPR, XANES and cyclic voltammetry confirmed the presence of a homoleptic Ni(I)-olefin complex....

Description complète

Enregistré dans:
Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Schwab, M. M., Himmel, D., Kacprzak, S., Kratzert, D., Radtke, V., Weis, P., Ray, K., Scheidt, E.-W., Scherer, W., de Bruin, B., Weber, S., Krossing, I.
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5531756/
https://ncbi.nlm.nih.gov/pubmed/26458726
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506475
Tags: Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!

Documents similaires