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[Ni(cod)(2)][Al(OR(F))(4)], a Source for Naked Ni(I) Chemistry
The straightforward synthesis of the cationic, purely organometallic Ni(I)-salt [Ni(cod)(2)](+)[Al(OR(F))(4)](–) was realized through a reaction between Ni(cod)(2) and Ag[Al(OR(F))(4)]. Crystal structure, EPR, XANES and cyclic voltammetry confirmed the presence of a homoleptic Ni(I)-olefin complex....
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| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5531756/ https://ncbi.nlm.nih.gov/pubmed/26458726 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506475 |
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