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A cobalt(ii) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior
The bifunctional salt [Co(terpy)(2)](TCNQ)(3)·CH(3)CN (terpy = 2,2′;6′,2′′-terpyridine, TCNQ = 7,7,8,8-tetracyanoquino-dimethane) exhibits a high room temperature conductivity of 0.13 S cm(–1) and an anomaly in conductivity at ∼190 K as evidenced by variable temperature structural, magnetic and cond...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5530863/ https://ncbi.nlm.nih.gov/pubmed/28808532 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03547c |
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