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Cytosine Iminyl Radical (cytN•) Formation via Electron Induced Debromination of 5-Bromocytosine: A DFT and Gaussian 4 study

Halogen-substituted pyrimidines, such as 5-bromouracil and 5-iodouracil, have been used as radio therapeutic (RT) agents in cancer treatment. The radiosensitizer activity of 5-bromouracil is attributed to its reaction with electron which produce the highly reactive uracil-5-yl radical by dissociatin...

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Détails bibliographiques
Publié dans:J Phys Chem A
Auteurs principaux: Kumar, Anil, Sevilla, M. D.
Format: Artigo
Langue:Inglês
Publié: 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5521985/
https://ncbi.nlm.nih.gov/pubmed/28586202
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.7b04034
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