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Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence
[Image: see text] Coupling reactions between benzylamines and boronic esters have been investigated. ortho-Lithiated benzylamines react with boronic esters and a N-activator to afford ortho-substituted benzylic boronic esters with formal 1,1′-benzylidene insertion into the C–B bond. The reaction occ...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical
Society
2017
|
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5520102/ https://ncbi.nlm.nih.gov/pubmed/28661133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05880 |
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