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Chemoselectivity in the Dehydrocoupling Synthesis of Higher Molecular Weight Polysilanes
The Cp(2)ZrCl(2)/2 BuLi catalyzed co-polymerization of H(2)MeSiSiMeH(2) and PhSiH(3) was compared to the homo-polymerization of H(2)MeSiSiPhH(2). In contrast to the co-polymerization, which gave molecular weights comparable to homo-polymerization of phenylsilane, the reaction of 1-methyl-2-phenyldis...
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| Publicado no: | Materials (Basel) |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Molecular Diversity Preservation International
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5513459/ https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma3021125 |
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