The role of the 5f valence orbitals of early actinides in chemical bonding

One of the long standing debates in actinide chemistry is the level of localization and participation of the actinide 5f valence orbitals in covalent bonds across the actinide series. Here we illuminate the role of the 5f valence orbitals of uranium, neptunium and plutonium in chemical bonding using...

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Bibliografiska uppgifter
I publikationen:Nat Commun
Huvudupphovsmän: Vitova, T., Pidchenko, I., Fellhauer, D., Bagus, P. S., Joly, Y., Pruessmann, T., Bahl, S., Gonzalez-Robles, E., Rothe, J., Altmaier, M., Denecke, M. A., Geckeis, H.
Materialtyp: Artigo
Språk:Inglês
Publicerad: Nature Publishing Group 2017
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5504295/
https://ncbi.nlm.nih.gov/pubmed/28681848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms16053
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