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Palladium carbene complexes as persistent radicals
A series of palladium(ii) radical carbene complexes, [PC˙(sp(2))P]PdI, [PC˙(sp(2))P]PdBr, and [PC˙(sp(2))P]PdCl (PC(sp(3))H(2)P = bis[2-(di-iso-propylphosphino)-phenyl]methane), is described. Compound [PC˙(sp(2))P]PdI dimerizes to {[PC(sp(2))P]PdI}(2) in the solid state, akin to the formation of Gom...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5500858/ https://ncbi.nlm.nih.gov/pubmed/28717474 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01441g |
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