Homochiral Self‐Sorted and Emissive Ir(III) Metallo‐Cryptophanes

The racemic ligands (±)‐tris(isonicotinoyl)‐cyclotriguaiacylene (L1), or (±)‐tris(4‐pyridyl‐methyl)‐cyclotriguaiacylene (L2) assemble with racemic (Λ,Δ)‐[Ir(ppy)(2)(MeCN)(2)](+), in which ppy=2‐phenylpyridinato, to form [{Ir(ppy)(2)}(3)(L)(2)](3+) metallo‐cryptophane cages. The crystal structure of...

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Bibliographic Details
Published in:Chemistry
Main Authors: Pritchard, Victoria E., Rota Martir, Diego, Oldknow, Samuel, Kai, Shumpei, Hiraoka, Shuichi, Cookson, Nikki J., Zysman‐Colman, Eli, Hardie, Michaele J.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2017
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5499720/
https://ncbi.nlm.nih.gov/pubmed/28370620
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201701348
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