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Homochiral Self‐Sorted and Emissive Ir(III) Metallo‐Cryptophanes
The racemic ligands (±)‐tris(isonicotinoyl)‐cyclotriguaiacylene (L1), or (±)‐tris(4‐pyridyl‐methyl)‐cyclotriguaiacylene (L2) assemble with racemic (Λ,Δ)‐[Ir(ppy)(2)(MeCN)(2)](+), in which ppy=2‐phenylpyridinato, to form [{Ir(ppy)(2)}(3)(L)(2)](3+) metallo‐cryptophane cages. The crystal structure of...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5499720/ https://ncbi.nlm.nih.gov/pubmed/28370620 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201701348 |
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