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Production of stealthin C involves an S–N-type Smiles rearrangement
The kinamycin family of aromatic polyketide natural products contains an atypical angucycline ring system substituted with a diazo group. The enzymatic chemistry involved in constructing both of these structural features has been largely unexplored. Here we report the in vivo and in vitro production...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2017
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5498114/ https://ncbi.nlm.nih.gov/pubmed/28191843 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b10586 |
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