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Facile Smiles-type rearrangement in radical cations of N-acyl arylsulfonamides and analogs
RATIONALE: N-Alkylation of sulfonylbenzamides was reported recently to cause a dramatic and surprising change in electron ionization mass spectrometry (EIMS), leading to a closed-shell base peak. Only an incomplete, speculative mechanism was available at that time. The fragmentation mechanism is det...
Gardado en:
| Publicado en: | Rapid Commun Mass Spectrom |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2014
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096379/ https://ncbi.nlm.nih.gov/pubmed/24573815 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/rcm.6850 |
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