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Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex

The search for novel, atom-economic methods for the formation of C–C bonds is of crucial importance in synthetic chemistry. Especially attractive are reactions where C–C bonds are formed through C–H activation, but the coupling of unactivated, alkane-type C(sp(3) )–H bonds remains an unsolved challe...

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Pubblicato in:Chem Sci
Autori principali: Polukeev, Alexey V., Marcos, Rocío, Ahlquist, Mårten S. G., Wendt, Ola F.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5496475/
https://ncbi.nlm.nih.gov/pubmed/28717458
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03839h
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