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Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates

Since their discovery by Bode and Glorius in 2004, N-heterocyclic carbene catalyzed conjugate umpolung reactions of α,β-enals have been postulated to involve the formation of diamino dienols (“homoenolates”) and/or azolium enolates (“enolates”), typically followed by addition to electrophiles, e.g....

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yatham, Veera Reddy, Neudörfl, Jörg-M., Schlörer, Nils E., Berkessel, Albrecht
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5496186/
https://ncbi.nlm.nih.gov/pubmed/28706717
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01027f
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