Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes

Cr(i)Cl is a very unstable species. The present work describes the stabilisation of Cr(i)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(i). One electron reduction of (cAAC)(...

Descrizione completa

Salvato in:
Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Samuel, Prinson P., Neufeld, Roman, Chandra Mondal, Kartik, Roesky, Herbert W., Herbst-Irmer, Regine, Stalke, Dietmar, Demeshko, Serhiy, Meyer, Franc, Rojisha, Vallyanga Chalil, De, Susmita, Parameswaran, Pattiyil, Stückl, A. Claudia, Kaim, Wolfgang, Christian, Jonathan H., Bindra, Jasleen K., Dalal, Naresh S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
Soggetti:
Chemistry
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5490427/
https://ncbi.nlm.nih.gov/pubmed/28706686
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00646e
Tags: Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !

Documenti analoghi