Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes

Cr(i)Cl is a very unstable species. The present work describes the stabilisation of Cr(i)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(i). One electron reduction of (cAAC)(...

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Foilsithe in:Chem Sci
Main Authors: Samuel, Prinson P., Neufeld, Roman, Chandra Mondal, Kartik, Roesky, Herbert W., Herbst-Irmer, Regine, Stalke, Dietmar, Demeshko, Serhiy, Meyer, Franc, Rojisha, Vallyanga Chalil, De, Susmita, Parameswaran, Pattiyil, Stückl, A. Claudia, Kaim, Wolfgang, Christian, Jonathan H., Bindra, Jasleen K., Dalal, Naresh S.
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2015
Ábhair:
Chemistry
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5490427/
https://ncbi.nlm.nih.gov/pubmed/28706686
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00646e
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