Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes

Cr(i)Cl is a very unstable species. The present work describes the stabilisation of Cr(i)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(i). One electron reduction of (cAAC)(...

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Publicat a:Chem Sci
Autors principals: Samuel, Prinson P., Neufeld, Roman, Chandra Mondal, Kartik, Roesky, Herbert W., Herbst-Irmer, Regine, Stalke, Dietmar, Demeshko, Serhiy, Meyer, Franc, Rojisha, Vallyanga Chalil, De, Susmita, Parameswaran, Pattiyil, Stückl, A. Claudia, Kaim, Wolfgang, Christian, Jonathan H., Bindra, Jasleen K., Dalal, Naresh S.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5490427/
https://ncbi.nlm.nih.gov/pubmed/28706686
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00646e
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