Transition-Metal-Free Formation of C–E Bonds (E = C, N, O, S) and Formation of C–M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C–F Bond Activation

Herein, a recently reported polyfluoroalkenyl imidazolium salt is shown to react with nitrogen-, oxygen- and sulfur-based nucleophiles at the C(β) position in a stereoselective and regioselective fashion, without the use of a transition metal. In contrast, reactivity with 1-methylimidazole demonstra...

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Bibliografische gegevens
Gepubliceerd in:Organometallics
Hoofdauteurs: Leclerc, Matthew C., Gabidullin, Bulat M., Da Gama, Jason G., Daifuku, Stephanie L., Iannuzzi, Theresa E., Neidig, Michael L., Baker, R. Tom
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2017
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488806/
https://ncbi.nlm.nih.gov/pubmed/28670045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.6b00908
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