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Transition-Metal-Free Formation of C–E Bonds (E = C, N, O, S) and Formation of C–M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C–F Bond Activation
Herein, a recently reported polyfluoroalkenyl imidazolium salt is shown to react with nitrogen-, oxygen- and sulfur-based nucleophiles at the C(β) position in a stereoselective and regioselective fashion, without the use of a transition metal. In contrast, reactivity with 1-methylimidazole demonstra...
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| Publicado no: | Organometallics |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5488806/ https://ncbi.nlm.nih.gov/pubmed/28670045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.6b00908 |
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