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Enantioselective Cyanation of Benzylic C–H Bonds via Copper-Catalyzed Radical Relay
Direct methods for stereoselective functionalization of C(sp(3))–H bonds in complex organic molecules could facilitate much more efficient preparation of therapeutics and agrochemicals. Here, we report a copper-catalyzed radical relay pathway for enantioselective conversion of benzylic C–H bonds int...
Shranjeno v:
| izdano v: | Science |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5488708/ https://ncbi.nlm.nih.gov/pubmed/27701109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf7783 |
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