Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air

Disclosed herein is the first general chemo‐ and site‐selective alkylation of C−Br bonds in the presence of COTf, C−Cl and other potentially reactive functional groups, using the air‐, moisture‐, and thermally stable dinuclear Pd(I) catalyst, [Pd(μ‐I)PtBu(3)](2). The bromo‐selectivity is independent...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Kalvet, Indrek, Sperger, Theresa, Scattolin, Thomas, Magnin, Guillaume, Schoenebeck, Franziska
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2017
Gaiak:
Communications
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488304/
https://ncbi.nlm.nih.gov/pubmed/28508520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701691
Etiketak: Etiketa erantsi
Etiketarik gabe, Izan zaitez lehena erregistro honi etiketa jartzen!

Antzeko izenburuak