Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air

Disclosed herein is the first general chemo‐ and site‐selective alkylation of C−Br bonds in the presence of COTf, C−Cl and other potentially reactive functional groups, using the air‐, moisture‐, and thermally stable dinuclear Pd(I) catalyst, [Pd(μ‐I)PtBu(3)](2). The bromo‐selectivity is independent...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Kalvet, Indrek, Sperger, Theresa, Scattolin, Thomas, Magnin, Guillaume, Schoenebeck, Franziska
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2017
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488304/
https://ncbi.nlm.nih.gov/pubmed/28508520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701691
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