Caricamento...
Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air
Disclosed herein is the first general chemo‐ and site‐selective alkylation of C−Br bonds in the presence of COTf, C−Cl and other potentially reactive functional groups, using the air‐, moisture‐, and thermally stable dinuclear Pd(I) catalyst, [Pd(μ‐I)PtBu(3)](2). The bromo‐selectivity is independent...
Salvato in:
| Pubblicato in: | Angew Chem Int Ed Engl |
|---|---|
| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2017
|
| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5488304/ https://ncbi.nlm.nih.gov/pubmed/28508520 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701691 |
| Tags: |
Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !
|