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Base Catalysis Enables Access to α,α-Difluoroalkylthioethers
A nucleophilic addition reaction of aryl thiols to readily available β,β-difluorostyrenes provides α,α-difluoroalkylthioethers. The reaction proceeds through an unstable anionic intermediate, prone to eliminate fluoride and generate α-fluorovinylthioethers. However, the use of base-catalysis overcom...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5485667/ https://ncbi.nlm.nih.gov/pubmed/28332397 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00386 |
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