Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts

N-Aryl phenoxazines have been synthesized and introduced as strongly reducing metal-free photoredox catalysts in organocatalyzed atom transfer radical polymerization for the synthesis of well-defined polymers. Experiments confirmed quantum chemical predictions that, like their dihydrophenazine analo...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Pearson, Ryan M., Lim, Chern-Hooi, McCarthy, Blaine G., Musgrave, Charles B., Miyake, Garret M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5485656/
https://ncbi.nlm.nih.gov/pubmed/27554292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08068
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