Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization

Photoexcited intramolecular charge transfer (CT) states in N,N-diaryl dihydrophenazine photoredox catalysts are accessed through catalyst design and investigated through combined experimental studies and density functional theory (DFT) calculations. These CT states are reminiscent of the metal to li...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Lim, Chern-Hooi, Ryan, Matthew D., McCarthy, Blaine G., Theriot, Jordan C., Sartor, Steven M., Damrauer, Niels H., Musgrave, Charles B., Miyake, Garret M.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2016
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488861/
https://ncbi.nlm.nih.gov/pubmed/27973788
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11022
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