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Palladium-Catalyzed, Aminoquinoline-Directed Arylation of Phosphonamidate and Phosphinic Amide sp(3) C-H Bonds
Aminoquinoline-directed, palladium-catalyzed sp(3) C–H bond arylation in phosphonamidates and phosphinic amides is reported. The reaction employs Pd(OAc)(2) catalyst at 10 mol % loading and cesium phosphate or potassium carbonate base in 1,2-dichlorobenzene solvent. Directing group can be removed un...
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發表在: | Chem Commun (Camb) |
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Main Authors: | , |
格式: | Artigo |
語言: | Inglês |
出版: |
2017
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主題: | |
在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5479433/ https://ncbi.nlm.nih.gov/pubmed/28394374 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc02063e |
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