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Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp(3))–H bonds with acetonitrile
The direct cyanomethylation of unactivated sp(3) C–H bonds of aliphatic amides was achieved via palladium catalysis assisted by a bidentate directing group with good functional group compatibility. This process represents the first example of the direct cross-coupling of sp(3) C–H bonds with acetoni...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5477045/ https://ncbi.nlm.nih.gov/pubmed/28660057 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04066c |
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