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A complex with nitrogen single, double, and triple bonds to the same chromium atom: synthesis, structure, and reactivity

A nitrogen-based analogue of the Schrock and Clark “yl-ene-yne” complex, W(CBu(t))(CHBu(t))(CH(2)Bu(t))(dmpe), has been prepared. The new complex is the nitrido, imido, amido anion [NCr(NPh)(NPr(i)(2))(2)](–), which was structurally characterized with the [K(crypt-2.2.2)](+) counterion. The “Cr–N 1-...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Beaumier, Evan P., Billow, Brennan S., Singh, Amrendra K., Biros, Shannon M., Odom, Aaron L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5477034/
https://ncbi.nlm.nih.gov/pubmed/28660023
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04608d
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