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A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds
A highly tunable radical-mediated reaction system for the functionalization of tertiary aliphatic C–H bonds was developed. Reactions of various substrates with the Zhdankin azidoiodane reagent 1, Ru(bpy)(3)Cl(2), and visible light irradiation at room temperature gave C–H azidated or halogenated prod...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5477033/ https://ncbi.nlm.nih.gov/pubmed/28660040 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04169d |
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