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Electronic π‐to‐π* Excitations of Rhodamine Dyes Exhibit a Time‐Dependent Kohn–Sham Theory “Cyanine Problem”

The longest‐wavelength π‐to‐π* electronic excitations of rhodamine‐like dyes (RDs) with different group 16 heteroatoms (O, S, Se, Te) have been investigated. Time‐dependent Kohn–Sham theory (TDKST) calculations were compared with coupled‐cluster (CC) and equations‐of‐motion (EOM) CC results for π‐to...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Moore, Barry, Schrader, Robert L., Kowalski, Karol, Autschbach, Jochen
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5474673/
https://ncbi.nlm.nih.gov/pubmed/28638771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201700046
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