Metal–Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal–Organic Framework

[Image: see text] We report a hafnium-containing MOF, hcp UiO-67(Hf), which is a ligand-deficient layered analogue of the face-centered cubic fcu UiO-67(Hf). hcp UiO-67 accommodates its lower ligand:metal ratio compared to fcu UiO-67 through a new structural mechanism: the formation of a condensed “...

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Publicat a:J Am Chem Soc
Autors principals: Cliffe, Matthew J., Castillo-Martínez, Elizabeth, Wu, Yue, Lee, Jeongjae, Forse, Alexander C., Firth, Francesca C. N., Moghadam, Peyman Z., Fairen-Jimenez, David, Gaultois, Michael W., Hill, Joshua A., Magdysyuk, Oxana V., Slater, Ben, Goodwin, Andrew L., Grey, Clare P.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5469521/
https://ncbi.nlm.nih.gov/pubmed/28343394
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00106
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