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Flexibility transition and guest-driven reconstruction in a ferroelastic metal–organic framework
The metal–organic framework copper(i) tricyanomethanide, Cu(tcm), undergoes a ferroelastic transition on cooling below T(f) = 240 K. Thermal expansion measurements reveal an order-of-magnitude variation in framework flexibility across T(f). The low-temperature phase α-Cu(tcm) exhibits colossal posit...
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| Publicado en: | CrystEngComm |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
The Royal Society of Chemistry
2014
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4304274/ https://ncbi.nlm.nih.gov/pubmed/25632268 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4ce01572j |
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