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Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel walls

A metal–organic framework (MOF) with one-dimensional channels of approximately hexagonal cross-section [Ag(2)(O(2)CCF(2)CF(2)CO(2))(TMP)] 1 (TMP =2,3,5,6-tetramethylpyrazine) has been synthesized with MeOH filling the channels in its as-synthesized form as [Ag(2)(O(2)CCF(2)CF(2)CO(2))(TMP)]·n(MeOH)...

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Bibliographic Details
Published in:Philos Trans A Math Phys Eng Sci
Main Authors: Smith, Rebecca, Vitórica-Yrezábal, Iñigo J., Hill, Adrian, Brammer, Lee
Format: Artigo
Language:Inglês
Published: The Royal Society 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5179934/
https://ncbi.nlm.nih.gov/pubmed/27895259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsta.2016.0031
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