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Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates
[Image: see text] A method for regio- and stereoselective anti-addition of the perfluoroalkyl and the triflate group of phenyl(perfluoroalkyl)iodonium triflates to alkynes is presented. The radical reaction uses cheap CuCl as a smart initiator and can be conducted in gram scale. The perfluoroalkyltr...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical Society
2017
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| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5460293/ https://ncbi.nlm.nih.gov/pubmed/28517935 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01215 |
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