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Solvent-Induced Polymorphism of Iron(II) Spin Crossover Complexes
Two new mononuclear iron(II) compounds (1) and (2) of the general formula [Fe(L)(2)](BF(4))(2)·nCH(3)CN (L = 4-(2-bromoethyn-1-yl)-2,6-bis(pyrazol-1-yl)pyridine, n = 1 for (1) and n = 2 for compound (2)), were synthesized. The room temperature crystallization afforded concomitant formation of two di...
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| Publié dans: | Materials (Basel) |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5456902/ https://ncbi.nlm.nih.gov/pubmed/28773709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma9070585 |
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