Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis

Solvent effects in a series of Fe(iii) spin crossover (SCO) complexes [Fe(qsal-I)(2)]OTf·sol (sol = MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is abrupt in 1 (following MeOH loss) and 2, gradual for 3 (T (1/2) = 199 K) and 4 (T (1/2) = 251 K) and incomplete, even up...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Phonsri, Wasinee, Harding, Phimphaka, Liu, Lujia, Telfer, Shane G., Murray, Keith S., Moubaraki, Boujemaa, Ross, Tamsyn M., Jameson, Guy N. L., Harding, David J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5433504/
https://ncbi.nlm.nih.gov/pubmed/28553537
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05317c
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