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Probing Transient Valence Orbital Changes with Picosecond Valence-to-Core X-ray Emission Spectroscopy

[Image: see text] We probe the dynamics of valence electrons in photoexcited [Fe(terpy)(2)](2+) in solution to gain deeper insight into the Fe–ligand bond changes. We use hard X-ray emission spectroscopy (XES), which combines element specificity and high penetration with sensitivity to orbital struc...

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Vydáno v:J Phys Chem C Nanomater Interfaces
Hlavní autoři: March, Anne Marie, Assefa, Tadesse A., Boemer, Christina, Bressler, Christian, Britz, Alexander, Diez, Michael, Doumy, Gilles, Galler, Andreas, Harder, Manuel, Khakhulin, Dmitry, Németh, Zoltán, Pápai, Mátyás, Schulz, Sebastian, Southworth, Stephen H., Yavaş, Hasan, Young, Linda, Gawelda, Wojciech, Vankó, György
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2017
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5453616/
https://ncbi.nlm.nih.gov/pubmed/28580048
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcc.6b12940
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