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Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles

The neutral dinuclear complexes [(η(5)-C(5)Me(5))(2)Rh(2)(μ-dhnq)Cl(2)] (1) and [(η(5)-C(5)Me(5))(2)Ir(2)(μ-dhnq)Cl(2)] (2) (dhnqH(2) = 5,8-dihydroxy-1,4-naphthoquinone) were obtained from the reaction of [(η(5)-C(5)Me(5))M(μ-Cl)Cl](2) (M = Rh, Ir) with dhnqH(2) in the presence of CH(3)COONa. Treatm...

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Dades bibliogràfiques
Publicat a:Materials (Basel)
Autors principals: Gupta, Gajendra, Murray, Benjamin S., Dyson, Paul J., Therrien, Bruno
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5452765/
https://ncbi.nlm.nih.gov/pubmed/28788394
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma6115352
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