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Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer

We report the direct chemoselective Brown-type oxidation of aryl organoboron systems containing two oxidizable boron groups. Basic biphasic reaction conditions enable selective formation and phase transfer of a boronic acid trihydroxyboronate in the presence of boronic acid pinacol (BPin) esters, wh...

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Dades bibliogràfiques
Publicat a:Chem Sci
Autors principals: Molloy, John J., Clohessy, Thomas A., Irving, Craig, Anderson, Niall A., Lloyd-Jones, Guy C., Watson, Allan J. B.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5452267/
https://ncbi.nlm.nih.gov/pubmed/28572912
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04014d
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