Sequence-defined oligo(ortho-arylene) foldamers derived from the benzannulation of ortho(arylene ethynylene)s

A Cu-catalyzed benzannulation reaction transforms ortho(arylene ethynylene) oligomers into ortho-arylenes. This approach circumvents iterative Suzuki cross-coupling reactions previously used to assemble hindered ortho-arylene backbones. These derivatives form helical folded structures in the solid-s...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lehnherr, Dan, Chen, Chen, Pedramrazi, Zahra, DeBlase, Catherine R., Alzola, Joaquin M., Keresztes, Ivan, Lobkovsky, Emil B., Crommie, Michael F., Dichtel, William R.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5450445/
https://ncbi.nlm.nih.gov/pubmed/28567248
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02520j
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