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Helicogenicity of solvents in the conformational equilibrium of oligo(m-phenylene ethynylene)s: Implications for foldamer research
A (R)-binaphthol tethered bis-hexameric oligo(m-phenylene ethynylene) foldamer was examined in 30 solvents to correlate the unfolded–folded conformational equilibrium to bulk solvent properties and specific solvent–chain interactions. The oligomer is soluble in a variety of solvents of intermediate...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2002
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC122720/ https://ncbi.nlm.nih.gov/pubmed/11917139 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.072642799 |
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