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Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase

The monoesters of carbonic acid are deemed to be unstable and decompose to alcohol and carbon dioxide. In spite of this, we here report the isolation of the elusive carbonic acid monoethyl ester (CAEE) as a pure solid from ethanolic solutions of potassium bicarbonate. The hemiester is surprisingly s...

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Detalhes bibliográficos
Publicado no:RSC Adv
Main Authors: Bernard, Jürgen, Köck, Eva-Maria, Huber, Roland G., Liedl, Klaus R., Call, Ludwig, Schlögl, Robert, Grothe, Hinrich, Loerting, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5450006/
https://ncbi.nlm.nih.gov/pubmed/28603608
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ra02792c
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