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Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase

The monoesters of carbonic acid are deemed to be unstable and decompose to alcohol and carbon dioxide. In spite of this, we here report the isolation of the elusive carbonic acid monoethyl ester (CAEE) as a pure solid from ethanolic solutions of potassium bicarbonate. The hemiester is surprisingly s...

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Bibliografiske detaljer
Udgivet i:RSC Adv
Main Authors: Bernard, Jürgen, Köck, Eva-Maria, Huber, Roland G., Liedl, Klaus R., Call, Ludwig, Schlögl, Robert, Grothe, Hinrich, Loerting, Thomas
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5450006/
https://ncbi.nlm.nih.gov/pubmed/28603608
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ra02792c
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