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(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles
Although BH(3) simply coordinates the endocyclic P of (phospholidino)phosphaketene 1(Dipp) , the bulkier B(C(6)F(5))(3) gives rise to a zwitterionic diphosphirenium, which is a novel type of 2π-electron aromatic system as shown by the calculated NICS values. While the reaction of 1(Dipp) with Na[PCO...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5437511/ https://ncbi.nlm.nih.gov/pubmed/28580107 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00300e |
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