(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles

Although BH(3) simply coordinates the endocyclic P of (phospholidino)phosphaketene 1(Dipp) , the bulkier B(C(6)F(5))(3) gives rise to a zwitterionic diphosphirenium, which is a novel type of 2π-electron aromatic system as shown by the calculated NICS values. While the reaction of 1(Dipp) with Na[PCO...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Hansmann, Max M., Ruiz, David A., Liu, Liu (Leo), Jazzar, Rodolphe, Bertrand, Guy
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2017
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5437511/
https://ncbi.nlm.nih.gov/pubmed/28580107
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00300e
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