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Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts

The first heterobimetallic sandwich-type aggregate formed by bowl-shaped corannulene trianion-radicals, C(20)H(10)˙(3–), has been synthesized using mixed-metal reduction of C(20)H(10). The product was crystallographically characterized to reveal the self-assembly of [Cs(+)//(C(20)H(10) (3–))/4K(+)/(...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Spisak, Sarah N., Rogachev, Andrey Yu., Zabula, Alexander V., Filatov, Alexander S., Clérac, Rodolphe, Petrukhina, Marina A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5413885/
https://ncbi.nlm.nih.gov/pubmed/28507689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05370j
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