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Theoretical basis for the stabilization of charges by radicals on electrified polymers

Quantum mechanical calculations at various levels of theory indicate that charges (both “+” and “−”) on organic polymers can be stabilized by radicals on nearby polymer chains. The stabilization mechanism is based on the formation of intermolecular odd-electron, two-center bonds with possible concom...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mazur, Tomasz, Grzybowski, Bartosz A.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5398273/
https://ncbi.nlm.nih.gov/pubmed/28451320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02672a
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