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Synthesis of Side-Chain Oxysterols and their Enantiomers through Cross-Metathesis Reactions of Δ(22) Steroids
A synthetic route that utilizes a cross-metathesis reaction with Δ(22) steroids has been developed to prepare sterols with varying C-27 side-chains. Natural sterols containing hydroxyl groups at the 25 and (25R)-26 positions were prepared. Enantiomers of cholesterol and (3β,25R)-26-hydroxycholestero...
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| Veröffentlicht in: | Steroids |
|---|---|
| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5398201/ https://ncbi.nlm.nih.gov/pubmed/28300584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.steroids.2017.03.002 |
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