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One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
A one‐pot protocol, effecting 14‐fold bromination with elemental bromine, has afforded copper β‐octabromo‐meso‐tris(2,6‐dibromo‐3,5‐dimethoxyphenyl)corrole, a new bis‐pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, wh...
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| Publicado no: | ChemistryOpen |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5390803/ https://ncbi.nlm.nih.gov/pubmed/28413755 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201600168 |
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