Mechanism of the selective functionalization of saturated hydrocarbons by Gif systems: relationship with methane monooxygenase.

Two intermediates, A and B, have been identified in the selective oxidation of saturated hydrocarbons to ketones by Gif-type systems. Intermediate A has been characterized as an Fev species with a secondary iron sigma-bond to carbon; it is captured by four different reagents or transformed into the...

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I whakaputaina i:	Proc Natl Acad Sci U S A
Ngā kaituhi matua:	Barton, D H, Csuhai, E, Doller, D, Ozbalik, N, Balavoine, G
Hōputu:	Artigo
Reo:	Inglês
I whakaputaina:	National Academy of Sciences 1990
Ngā marau:	Research Article
Urunga tuihono:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC53908/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/2333289/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.87.9.3401
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