Mechanism of the selective functionalization of saturated hydrocarbons by Gif systems: relationship with methane monooxygenase.
Two intermediates, A and B, have been identified in the selective oxidation of saturated hydrocarbons to ketones by Gif-type systems. Intermediate A has been characterized as an Fev species with a secondary iron sigma-bond to carbon; it is captured by four different reagents or transformed into the...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1990
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC53908/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/2333289/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.87.9.3401 |
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