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Multiple competing pathways for chemical reaction: drastic reaction shortcut for the self-catalytic double-helix formation of helicene oligomers

Competition among multiple pathways in a chemical reaction exhibits notable kinetic phenomena, particularly when amplification by self-catalysis is involved. A pseudoenantiomeric 1 : 1 mixture of an aminomethylene helicene (P)-tetramer and an (M)-pentamer formed enantiomeric hetero-double helices B...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Kushida, Yo, Saito, Nozomi, Shigeno, Masanori, Yamaguchi, Masahiko
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2017
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5390785/
https://ncbi.nlm.nih.gov/pubmed/28451281
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01893a
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